Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders     

Sanae Koizumi  Takehiko Hiraga  Chihiro Tachibana  Miki Tasaka  Tomonori Miyazaki  Tamio Kobayashi  Asako Takamasa  Naoki Ohashi  Satoru Sano 《Physics and Chemistry of Minerals》2010,37(8):505-518

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.  相似文献   

A 35 kyr record of organic matter composition and δ13C of n-alkanes in bog sediments close to Lake Baikal: Implications for paleoenvironmental studies     

Ryoshi Ishiwatari  Naoki Fujino  David Brincat  Shuichi Yamamoto  Hikaru Takahara  Koji Shichi  Sergey K. Krivonogov 《Organic Geochemistry》2009,40(1):51-60

We characterized the compositions of organic compounds in a Cheremushka bog sediment core (deposited over the last 35 kyr), located at the eastern coast of Lake Baikal, to obtain basic information about the terrestrial organic matter (OM) which contributed to Lake Baikal sediments. The bog sediment was analyzed for the molecular composition of n-alkanes, lignin phenols and n-C₂₄ to C₃₀ alkanoic acids, as well as the carbon isotopic composition of plant wax derived n-C₂₇ to C₃₃ alkanes.Concentrations of lignin phenols [vanillyl (V) plus syringyl (S) phenols] normalized to total organic carbon (TOC) in the Holocene are twice those for the last glacial maximum (LGM), while concentrations of TOC-normalized n-C₂₄ to C₃₀ alkanoic acids do not change markedly in this period. Thus, the ratio of lignin phenols to n-C₂₄ to C₃₀ alkanoic acids increases from the LGM to the Holocene. This result is essentially consistent with pollen analysis indicating an expansion of woody plants in the Holocene and a prevailing herb-abundant environment for the LGM. The δ¹³C values of n-C₂₇ to C₃₃ alkanes (e.g. ?29‰ to ?33‰ for C₃₁) indicate the presence of C₃-dominant plants throughout the core.The contribution of terrestrial OM to Lake Baikal sediments was estimated using the biomarkers, on the assumption that the OM in the bog sediments is a representative of the terrestrial OM around the lake. Hence, the estimation using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters indicates that 11–24% of the TOC in the Academician Ridge sediments is land-derived for both the Holocene and the LGM, which is similar to the estimates from C/N values of bulk OM. However, the estimates for terrestrial OM using the n-C₂₇ to C₃₃ alkane parameter are generally higher than those using lignin phenol or n-C₂₄ to C₃₀ alkanoic acid parameters. The difference is thought to be associated with the difference in source and behavior of these biomarkers.  相似文献   

Chemical characteristics of the lherzolitic shergottite Yamato 000097: magmatism on Mars inferred from the chemical compositions of shergottites   总被引：1，自引：1，他引：0  

Naoki Shirai  Mitsuru Ebihara 《Polar Science》2009,3(2):117-133

As a part of a consortium study, we analyzed the Martian meteorite Yamato (Y) 000097 by prompt gamma-ray analysis, instrumental neutron activation analysis, and instrumental photon activation analysis. For comparison, we also analyzed Allan Hills (ALH) 77005 using the same methods. The data confirm that Y000097 belongs to lherzolitic shergottites in terms of chemical composition. Although there exist slight differences in elemental abundances among lherzolitic shergottites due to differences in the modal abundances of constituent minerals, they have essentially the same chemical compositions, suggesting they are genetically related and experienced similar formation histories.Zr/Hf ratios obtained for Y000097 and ALH 77005 are subchondritic, consistent with values reported for other lherzolitic shergottites and olivine-phyric shergottites. Such fractionation can be explained by invoking clinopyroxene, ilmenite, or majorite in the petrogenesis of the shergottites' source material. CI-normalized Hf/Sm ratios obtained for Y000097 and ALH 77005 are 1.52 and 1.37, respectively, consistent with superchondritic Hf/Sm ratios reported for shergottites. Based on experimentally derived partition coefficients, majorite is the best candidate mineral for the fractionation of Hf and Sm in shergottites.  相似文献   

Middle Permian radiolarians from Anmenkou, Chaohu, Northeastern Yangtze platform, China     

Masao  Kametaka  Hiromi  Nagai  Sizhao  Zhu  Masamichi  Takebe 《Island Arc》2009,18(1):108-125

The biostratigraphy of the Middle Permian Gufeng Formation in the northeastern Yangtze platform is examined based on radiolarians. This study is concentrated on the Anmenkou section in the Chaohu area of Anhui Province, China. The Gufeng Formation is divided into the Phosphate Nodule-bearing Mudstone Member (PNMM) and the Siliceous Rock Member (SRM) in ascending order. The former primarily consists of mudstone including abundant phosphate nodules, and the latter consists mainly of alternating beds of chert, siliceous mudstone and mudstone, with intercalations of porous chert. Ammonoids in the mudstone of the lower PNMM are Wordian. Chert, siliceous mudstone and mudstone of the SRM include abundant radiolarians with sponge spicule assemblages suggestive of the Wordian–Capitanian. Albaillellaria are predominant in the lower SRM, while Entactinaria and Spumellaria are predominant in the middle and upper SRM. These radiolarians correspond to three radiolarian assemblage zones: Pseudoalbaillella longtanensis – Pseudoalbaillella fusiformis , Follicucullus monacanthus , and Follicucullus scholasticus – Ruzhencevispongus uralicus . The assemblage of radiolarians and sponge spicule fauna suggests a depositional depth of 150–500 m. The radiolarian fauna of the Gufeng Formation is considered to be representative of the relatively shallow, tropical radiolarian fauna of the Middle Permian eastern Paleotethys.  相似文献   

Foraminiferal evidence of submarine sediment transport and deposition by backwash during the 2004 Indian Ocean tsunami     

Daisuke  Sugawara  Koji  Minoura  Naoki  Nemoto  Shinji  Tsukawaki  Kazuhisa  Goto  Fumihiko  Imamura 《Island Arc》2009,18(3):513-525

Micropaleontological analysis of nearshore to offshore sediments recovered from the southwestern coast of Thailand was performed to clarify the submarine processes of sediment transport and deposition during the 2004 Indian Ocean tsunami. The distribution pattern of benthic foraminifers showed seaward migration after the tsunami event. Agglutinated foraminifers, which are characteristic of an intertidal brackish environment, were identified in the post-tsunami samples from foreshore to offshore zones. These suggest that sediments originally distributed in foreshore to nearshore zones were transported offshore due to the tsunami backwash. On the other hand, the distribution pattern of planktonic and benthic species living in offshore zones showed slight evidence of landward migration by the tsunami. This suggests that landward redistribution of sediments by the tsunami run-up did not occur in the offshore seafloor of the study area. Our results and a review of previous studies provide an interpretation of submarine sedimentation by tsunamis. It is possible that tsunami backwashes induce sediment flows that transport a large amount of coastal materials seaward. Thus, traces of paleotsunami backwashes can be identified in offshore sedimentary environments as the accumulation of allochthonous materials. This can be recognized as changes in benthic foraminiferal assemblages.  相似文献   

西南日本地区地壳P、S波速度结构与地震活动的关系   总被引：2，自引：1，他引：1       下载免费PDF全文

孙安辉  赵大鹏  池田伦治  陈颙  山田朗  陈棋福  大野裕记  西坂直树 《地球物理学进展》2008,23(4):1013-1022

选用密集的高精度地震台网Hi-net 2002～2004年记录的836个地震事件的23,895条P波和21,969条S波的到时资料,计算得到了日本西南地区水平分辨率约33 km,垂直分辨率4～15 km的三维地壳P波和S波速度结构,并进一步获得泊松比分布.研究表明,在大山火山下存在显著的低速异常,表明该火山可能是一个潜在的活火山.速度异常图像清楚地显示了菲律宾板块俯冲至西南日本地区下,其上方存在的低速高泊松异常表明可能有流体的存在,分析得出可能来自板块俯冲过程中的脱水作用.并进一步探讨了流体在地震孕育及触发的过程中可能起的重要作用.  相似文献   

Nutrient interleaving below the mixed layer of the Kuroshio Extension Front   总被引：1，自引：1，他引：0  

Takeyoshi Nagai  Sophie Clayton 《Ocean Dynamics》2017,67(8):1027-1046

Nitrate interleaving structures were observed below the mixed layer during a cruise to the Kuroshio Extension in October 2009. In this paper, we investigate the formation mechanisms for these vertical nitrate anomalies, which may be an important source of nitrate to the oligotrphoc surface waters south of the Kuroshio Extension Front. We found that nitrate concentrations below the main stream of the Kuroshio Extension were elevated compared to the ambient water of the same density (σ _?? = 23.5–25). This appears to be analogous to the “nutrient stream” below the mixed layer, associated with the Gulf Stream. Strong turbulence was observed above the vertical nitrate anomaly, and we found that this can drive a large vertical turbulent nitrate flux \(>\mathcal {O}\) (1 mmol N m^?2 day^?1). A realistic, high-resolution (2 km) numerical simulation reproduces the observed Kuroshio nutrient stream and nitrate interleaving structures, with similar lateral and vertical scales. The model results suggest that the nitrate interleaving structures are first generated at the western side of the meander crest on the south side of the Kuroshio Extension, where the southern tip of the mixed layer front is under frontogenesis. Lagrangian analyses reveal that the vertical shear of geostrophic and subinertial ageostrophic flow below the mixed layer tilts the existing along-isopycnal nitrate gradient of the Kuroshio nutrient stream to form nitrate interleaving structures. This study suggests that the multi-scale combination of (i) the lateral stirring of the Kuroshio nutrient stream by developed mixed layer fronts during fall to winter, (ii) the associated tilting of along-isopycnal nitrate gradient of the nutrient stream by subinertial shear, which forms vertical interleaving structures, and (iii) the strong turbulent diffusion above them, may provide a route to supply nutrients to oligotrophic surface waters on the south side of the Kuroshio Extension.  相似文献   

Dynamic analysis of structures with Maxwell model     

Tomohiko Hatada  Takuji Kobori  Masatoshi Ishida  Naoki Niwa 《地震工程与结构动力学》2000,29(2):159-176

A numerical method has been developed for the dynamic analysis of a tall building structure with viscous dampers. Viscous dampers are installed between the top of an inverted V‐shaped brace and the upper beam on each storey to reduce vibrations during strong disturbances like earthquakes. Analytically, it is modelled as a multi‐degree‐of freedom (MDOF) system with the Maxwell models. First, the computational method is formulated in the time domain by introducing a finite element of the Maxwell model into the equation of motion in the discrete‐time system, which is based on the direct numerical integration. Next, analyses for numerical stability and accuracy of the proposed method are discussed. The results show its numerical stability. Finally, the proposed method is applied to the numerical analysis of a realistic building structure to demonstrate its practical validity.  相似文献   

Siderophile element characteristics of acapulcoite–lodranites and winonaites: Implications for the early differentiation processes of their parent bodies     

Yoshihiro Hidaka  Naoki Shirai  Akira Yamaguchi  Mitsuru Ebihara 《Meteoritics & planetary science》2019,54(5):1153-1166

We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.  相似文献   

In memoriam—Hiroshi Fukuoka (1961–2018)     

Kyoji Sassa  Paolo Canuti  Kaoru Takara  Naoki Watanabe 《Landslides》2018,15(9):1905-1906

  相似文献